2025/09/09 by A. O. Shilov, Shilov, A. O., С. С. Савченко +7
Engineering · #Advancements in Semiconductor Devices and Circuit Design #FOS: Physical sciences #Materials Science (cond-mat.mtrl-sci) #Semiconductor materials and devices #Silicon and Solar Cell Technologies
paper · pdf · doi:10.48550/arxiv.2509.07419
openalex publication_date 2025/09/09 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28
Hafnium dioxide, also known as hafnia, is an extremely sought-after material in opto- and nanoelectronics for creating optical coatings and various functional media to have stable performance characteristics under varying thermal operating conditions. In this paper, we have investigated the behavior of the optical properties of hafnia thin films exhibiting an amorphous structure in a wide temperature range of 7-296 K. For the first time we have examined the temperature effects in the energy gap of HfO2 films and estimated the effective phonon energy of 30 meV responsible for observed thermally assisted shift of electronic levels. It has been shown that the electron-phonon interaction in the oxygen subsystem predominantly causes the observed changes. The obtained refractive index values for the tested films are established to be compatible with independent predicted data and to decrease as the temperature drops. The energy structure and electron-phonon interaction features that have been found are critical for forecasting how hafnia-thin-film-based optoelectronic devices will behave across a wide temperature range.