2021/04/19 by Ran Su, Zhipeng Wang, Li‐Na Zhu +11
Materials Science · #Ferroelectric and Piezoelectric Materials #Multiferroics and related materials #Electronic and Structural Properties of Oxides
paper · doi:10.1002/ange.202103112
Abstract Developing nano‐ferroelectric materials with excellent piezoelectric performance for piezocatalysts used in water splitting is highly desired but also challenging, especially with respect to reaching large piezo‐potentials that fully align with required redox levels. Herein, heteroepitaxial strain in BaTiO 3 nanoparticles with a designed porous structure is successfully induced by engineering their surface reconstruction to dramatically enhance their piezoelectricity. The strain coherence can be maintained throughout the nanoparticle bulk, resulting in a significant increase of the BaTiO 3 tetragonality and thus its piezoelectricity. Benefiting from high piezoelectricity, the as‐synthesized blue‐colored BaTiO 3 nanoparticles possess a superb overall water‐splitting activity, with H 2 production rates of 159 μmol g −1 h −1 , which is almost 130 times higher than that of the pristine BaTiO 3 nanoparticles. Thus, this work provides a generic approach for designing highly efficient piezoelectric nanomaterials by strain engineering that can be further extended to various other perovskite oxides, including SrTiO 3 , thereby enhancing their potential for piezoelectric catalysis.